If near a river, then Market, Harbor Aquaduct. If no river, then Harbor, Aquaduct, Market, but probably for slightly different reasons than others here have posted for. With a river you can utilize the extra gold and use it with the Market. However, for the rest of my post I will assume there's no river nearby.
First: Harbor opens up the use of the water tiles. Without it, it's just another land city using up tiles. With an Aquaduct you can grow, and especially powerful: You can add pop via Workers. Pump it up to size 12, and share the land shield tiles until you finish the Market/Lib (if you haven't already built them before this situation arises).
You can always pop out a few Workers if you reach siez 6 before your Aqua finishes (likely), and add them back later. I like building lots and lots and lots of Workers though... insta-pop boom when you need it.
First: Harbor opens up the use of the water tiles. Without it, it's just another land city using up tiles. With an Aquaduct you can grow, and especially powerful: You can add pop via Workers. Pump it up to size 12, and share the land shield tiles until you finish the Market/Lib (if you haven't already built them before this situation arises).
You can always pop out a few Workers if you reach siez 6 before your Aqua finishes (likely), and add them back later. I like building lots and lots and lots of Workers though... insta-pop boom when you need it.

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