The Altera Centauri collection has been brought up to date by Darsnan. It comprises every decent scenario he's been able to find anywhere on the web, going back over 20 years.
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Call To Power 2 Cradle 3+ mod in progress: https://apolyton.net/forum/other-games/call-to-power-2/ctp2-creation/9437883-making-cradle-3-fully-compatible-with-the-apolyton-edition
I would guess that you haven't run the game yet. The .ini file is generated the first time you run the game.
If you have the folder sorted alphabeticaly it should be right below the executable like this
Civilization3.exe
Civilization3.Ini
If you only 'Civilization3' then you have extensions turned off which is a bad idea that Microsoft has. They want to protect you from yourself by making it impossible to track files by extension.
You should turn visible extensions on but if you don't you can still find the file as the type is "configuration settings" for all .ini files and it should be one or two KB in size.
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